Amazon gives non-Prime members free shipping at $35 or more of eligible items. Instead of simply letting users get the product with free shipping, they’ve added a discount that prices it exactly one cent below the $35 limit, while only subsidizing the price with $3.38, which is about half of what they’ll then charge you for shipping.
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It might be your physical address. I’m not sure how long youve lived there but maybe someone who lived there before you ran a bunch of charge back scams or something and got put on a list somewhere. If that is the case then your address plus prepaid card and privacy respecting email will throw up red flags for any retailer that uses that list.
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I’ll put my bet that your computer is throwing false flags with payment/fraud detection. It could be the VPN and JavaScript blocking things.